Chemistry(Atomic Structure)

Created by Sam Kshitij

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What are energy levels in Bohr's theory?

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Energy levels are fixed orbits around the nucleus where electrons can exist, with the closest orbit having the lowest energy.

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Bohr's Theory of the Atom

What are energy levels in Bohr's theory?

Energy levels are fixed orbits around the nucleus where electrons can exist, with the closest orbit having the lowest energy.

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Rutherford's Nuclear Model of Atom

What is the significance of the nucleus in Rutherford's conclusions?

Rutherford concluded that the nucleus is a very small portion of the atom that contains concentrated positive charge, which is responsible for repelling and deflecting a few positively charged alpha particles during his experiment.

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Quantum Numbers

What is the Magnetic Spin Quantum Number (ms)?

It determines the orientation of the spin and can have values of +1/2 or -1/2.

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Hydrogen Spectrum and Series

What is the Paschen Series?

The Paschen Series is the series of spectral lines observed when excited electrons in hydrogen atoms fall from higher energy levels to the third energy level, and these lines are observed in the infra-red region.

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Planck's Quantum Theory

What is the definition of quantization?

Quantization is the restriction of a property to discrete values rather than continuous values.

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Hydrogen Spectrum and Series

What is the Lyman Series?

The Lyman Series refers to the series of spectral lines observed when excited electrons in hydrogen atoms fall from higher energy levels to the first energy level, and these lines are observed in the ultraviolet region.

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Bohr's Theory of the Atom

What is the formula for potential energy in an atom?

Potential energy is given by U = -K/e^2 * r.

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Quantum Numbers

What is the Schrodinger wave equation?

The Schrodinger wave equation is a fundamental equation that describes how the quantum state of a physical system changes over time.

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Anomalous Electronic Configurations

What is an anomalous electronic configuration?

An anomalous electronic configuration refers to exceptions in the expected electron configurations, such as those seen in Chromium (24) and Copper (29).

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Electromagnetic Spectrum

What is the relationship between frequency and wavelength?

The relationship is given by the formula C = νλ, where C is the speed of light, ν is the frequency, and λ is the wavelength.

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Thomson Model of Atom

What is the Thomson Model of Atom?

The Thomson Model of Atom, proposed by J.J. Thomson, describes the atom as a uniform sphere of positive charge with electrons embedded within it, resembling a 'raisin pudding' where the positive charge is the pudding and the electrons are the raisins.

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Pauli Exclusion Principle and Aufbau Principle

What does the Pauli Exclusion Principle state?

No two electrons in an atom can have the same four quantum numbers, meaning an orbital can hold a maximum of two electrons with opposite spin quantum numbers.

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Quantum Numbers

What does the Magnetic Quantum Number (m) determine?

It determines the orientation of the orbital and can take integer values between -l and +l, including 0.

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Hydrogen Spectrum and Series

What is the Brackett Series?

The Brackett Series consists of spectral lines observed when excited electrons in hydrogen atoms fall from higher energy levels to the fourth energy level, and these lines are also observed in the infra-red region.

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Rutherford's Nuclear Model of Atom

What are nucleons?

Nucleons are the particles found in the nucleus of an atom, specifically protons and neutrons, which are much heavier than electrons.

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Quantum Numbers

How does the distance of maximum probability of finding an electron change with principal quantum number?

The distance at which the maximum probability of finding an electron increases with an increase in the value of the principal quantum number.

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Aufbau Principle and Pauli Exclusion Principle

What is the Aufbau principle?

The Aufbau principle states that in the ground state of atoms, orbitals are filled in the order of their increasing energies.

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Quantum Numbers

What does the azimuthal quantum number define?

The azimuthal quantum number defines the three-dimensional shape of the orbital.

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Electromagnetic Spectrum

What is the wave number formula?

The wave number (ν) is given by the formula ν = 1/λ, where λ is the wavelength.

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Rutherford's Nuclear Model of Atom

What is the Rutherford's Nuclear Model of Atom?

An atom consists of a tiny positively charged center called the nucleus, which contains protons and neutrons (nucleons). The mass of the atom lies in its nucleus, and electrons revolve around the nucleus in fixed circular paths called orbits.

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Hydrogen Spectrum and Series

What is the Balmer Series?

The Balmer Series refers to the series of spectral lines observed when excited electrons in hydrogen atoms fall from higher energy levels to the second energy level, and these lines are observed in the visible region.

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Quantum Numbers

What is the Magnetic Quantum Number?

The Magnetic Quantum Number (mi) describes the magnetic orientation of an orbital and can take values from -l to +l.

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Bohr's Theory of the Atom

What does Bohr's Theory state about electron energy levels?

Bohr's Theory states that an electron does not radiate energy while in a stable orbit and only radiates or absorbs energy when moving between orbits, with energy being radiated when moving towards the nucleus.

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Quantum Numbers

What is Heisenberg's uncertainty principle?

Heisenberg's uncertainty principle states that it is impossible to determine simultaneously the exact position and momentum of an electron.

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Quantum Numbers

What does the principal quantum number (n) determine?

The principal quantum number (n) determines the size and energy of the orbit.

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Quantum Numbers

What is angular momentum of an electron?

The angular momentum of an electron is given by the formula L = nħ, where n is the principal quantum number and ħ is the reduced Planck's constant.

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Pauli Exclusion Principle and Aufbau Principle

What is the Aufbau Principle?

Electrons are filled in various orbitals in increasing order of their energies, with the lowest energy orbital filled first.

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Planck's Quantum Theory

What does Planck's Quantum Theory state about energy?

Energy is radiated or absorbed by a body not continuously but in small packets called quanta. In the case of light, the quantum is called a photon, and the energy of a quantum is directly proportional to the frequency of the radiation.

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Quantum Numbers

What is the Angular Momentum Quantum Number?

The Angular Momentum Quantum Number (l) determines the shape of the orbital and can have values from 0 to n-1.

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Bohr's Theory of the Atom

What is the definition of the Centrifugal force in relation to the nucleus?

Centrifugal forces acting away from the nucleus is equal to 2 mv/r.

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Hydrogen Spectrum and Series

What does the Stark effect refer to?

The Stark effect is the splitting of spectral lines under the influence of an electric field.

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Quantum Numbers

What are the conditions that a wave function must satisfy?

A wave function must be continuous, finite, single-valued at any point, and the probability of finding the electron over the space must equal one.

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Thomson Model of Atom

What is J.J. Thomson's atomic model also known as?

J.J. Thomson's atomic model is also called the 'watermelon', 'plum pudding', or 'raisin pudding' model.

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Planck's Quantum Theory

What is the energy associated with a photon?

The energy associated with a photon is given by the formula E = nhν, where h is Planck's constant and ν is the frequency.

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Rutherford's Gold Foil Experiment

What are alpha particles?

Alpha particles are positively charged helium ions with a charge of +2 and a mass of 4u, emitted during the radioactive decay of unstable elements like Uranium.

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Rutherford's Gold Foil Experiment

What did Rutherford's Gold Foil Experiment demonstrate?

Rutherford's Gold Foil Experiment demonstrated that most of the atom's space is empty, as most alpha particles passed through the foil undeflected, while a small fraction was deflected, indicating a concentrated positive charge in a small volume called the nucleus.

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Planck's Quantum Theory

What is Planck's constant (h)?

Planck's constant (h) is a fundamental constant in quantum mechanics, valued at 6.6262 × 10 –34 Js.

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Electromagnetic Spectrum

What is the electromagnetic spectrum?

The electromagnetic spectrum is an arrangement of all kinds of radiations in order of decreasing frequency or increasing wavelength, differing from one another in wavelength or frequency.

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Hydrogen Spectrum and Series

What is the Rydberg Formula?

The Rydberg Formula is used to calculate the wavelengths of spectral lines in hydrogen and is expressed as 1/λ = R_H(1/n_1^2 - 1/n_2^2), where R_H is the Rydberg constant, n_1 is the lower energy level, and n_2 is the higher energy level.

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Quantum Numbers

What is the maximum probability distance for the 1s and 2s orbitals?

For the 1s orbital, the maximum probability is at 0.53 Å, and for the 2s orbital, it is at about 2.6 Å.

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Aufbau Principle and Pauli Exclusion Principle

What does the Pauli exclusion principle state?

The Pauli exclusion principle states that no two electrons can have the same set of four quantum numbers.

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Quantum Numbers

What are the values of 'l' in subshell notation?

The values of 'l' are 0, 1, 2, 3, 4, 5, corresponding to subshells s, p, d, f, g, h respectively.

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Quantum Numbers

What is the Spin Quantum Number?

It indicates the direction in which an electron revolves and is a magnetic property that is quantized, having two permitted values: +1/2 and -1/2, denoted by 's'.

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Quantum Numbers

What is the role of the Azimuthal Quantum Number (l)?

It identifies the subshell, determines the shape of the orbital, and is restricted to positive integers less than n.

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Quantum Numbers

What is the Stark Effect?

The Stark Effect is the splitting of spectral lines in an electric field.

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Quantum Numbers

What is the Electron radial probability distribution function (D)?

The Electron radial probability distribution function (D) is equal to 4πr²ψ².

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Quantum Numbers

How do you calculate the number of radial nodes?

The number of radial nodes is given by the formula n - l - 1.

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Thomson Model of Atom

What is the mass of an electron?

The mass of an electron is approximately 9.1094 × 10^-31 kg.

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Rutherford's Nuclear Model of Atom

What are nucleons?

Nucleons are the protons and neutrons present in the nucleus of an atom.

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Rutherford's Nuclear Model of Atom

What are isotopes?

Isotopes are atoms that have the same atomic number but different mass numbers.

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Rutherford's Nuclear Model of Atom

What does Coulomb's law describe?

Coulomb's law describes the electrostatic force of attraction between the nucleus and the electron in a hydrogen atom.

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Stability of Half Filled and Completely Filled Orb...

What is the significance of Half Filled and Completely Filled Orbitals?

They exhibit symmetrical distribution of electrons, leading to greater stability due to maximum exchange energy when electrons can exchange positions.

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Hydrogen Spectrum and Series

What is the significance of the Balmer Formula?

The Balmer Formula provides a simple empirical relationship to calculate the wave number of any line in the visible spectrum of atomic hydrogen, using the Rydberg constant.

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Rutherford's Nuclear Model of Atom

What is the mass number?

The mass number is the total number of nucleons (protons and neutrons) in the nucleus of an atom.

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Planck's Quantum Theory

What does de Broglie's equation describe?

De Broglie's equation states that λ = h/p, where λ is the wavelength, h is Planck's constant, and p is the momentum.

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Thomson Model of Atom

What is the atomic theory of matter proposed by John Dalton?

The atomic theory of matter states that matter is composed of atoms, which are indivisible and indestructible particles.

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Quantum Numbers

What information does the magnetic quantum number provide?

The magnetic quantum number (m) gives information about the spatial orientation of the orbital.

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Planck's Quantum Theory

What is the work function (W)?

The work function (W) is the energy required to overcome the attractive forces on the electron in the metal.

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Quantum Numbers

What does the Principal Quantum Number (n) indicate?

It identifies the shell, determines the size and energy of the orbital, and the number of orbitals in the nth shell is equal to n².

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Quantum Numbers

What is the Zeeman Effect?

The Zeeman Effect is the splitting of spectral lines in a strong magnetic field, associated with the magnetic quantum number.

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Quantum Numbers

What is the Principal Quantum Number?

The Principal Quantum Number (n) specifies the location and energy of an electron, with possible values of 1, 2, 3, etc.

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Bohr's Theory of the Atom

What is the formula for the radius of the n-th orbit?

The radius of the n-th orbit is given by r_n = (n^2 * h^2) / (4 * π^2 * m * e^2) or r_n = 0.529 * n^2 A.

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Quantum Numbers

What is a radial node?

The surface at which the probability of finding an electron is zero is called a radial node.

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Aufbau Principle and Pauli Exclusion Principle

What is Hund's rule?

Hund's rule states that pairing of electrons in orbitals belonging to the same subshell does not take place until all the orbitals are singly occupied.

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Rutherford's Nuclear Model of Atom

What is the mass number (A)?

The mass number (A) is the total number of protons (Z) and neutrons (n) in the nucleus of an atom.

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Hydrogen Spectrum and Series

What is the Rydberg equation?

The Rydberg equation is used to predict the wavelengths of spectral lines in hydrogen and is given by ν = R(1/n1^2 - 1/n2^2), where R is the Rydberg constant.

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Hydrogen Spectrum and Series

What is the Pfund Series?

The Pfund Series is the series of spectral lines observed when excited electrons in hydrogen atoms fall from higher energy levels to the fifth energy level, and these lines are found in the infra-red region.

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Quantum Numbers

What is the Spin quantum number (s)?

The Spin quantum number (s) gives an idea about the spin of the electron and can take the values of +1/2 and -1/2.

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Quantum Numbers

What is the order of size of orbitals?

The size of the orbital increases in the order of 1s < 2s < 3s < 4s.

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Quantum Numbers

What is an atomic orbital?

An atomic orbital is the three-dimensional space around the nucleus where the probability of finding an electron is maximum.

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Rutherford's Nuclear Model of Atom

What is the atomic number (Z)?

The atomic number (Z) is the number of protons in the nucleus of an atom, which is also equal to the number of electrons in a neutral atom.

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Rutherford's Nuclear Model of Atom

What are isobars?

Isobars are atoms that have the same mass number but different atomic numbers.

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Planck's Quantum Theory

What is the photoelectric effect?

The photoelectric effect is the ejection of an electron from a metal surface when a photon of energy greater than the threshold energy strikes an electron in the atom.

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Bohr's Theory of the Atom

What are the drawbacks of Bohr's Theory?

Bohr's Theory could not explain the spectrum of multi-electron atoms, the Zeeman and Stark effects, the shape of molecules, or align with Heisenberg's uncertainty principle.

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Hydrogen Spectrum and Series

What is the Zeeman effect?

The Zeeman effect is the splitting of spectral lines under the influence of a magnetic field.

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Quantum Numbers

How many orbitals are in a given sublevel?

The number of orbitals in a given sublevel is given by 2l + 1, where l is the azimuthal quantum number.

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Planck's Quantum Theory

What is a black body?

A black body is a body that emits and absorbs all frequencies of electromagnetic radiation.

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